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The tunnel effect in chemistry 🔍
R. P. Bell (auth.) Springer US : Imprint : Springer, Softcover reprint of the original 1st ed. 1980, US, 1980
英语 [en] · PDF · 5.8MB · 1980 · 📘 非小说类图书 · 🚀/lgli/lgrs/nexusstc/scihub/zlib · Save
描述
The suggestion that quantum-mechanical tunnelling might be a significant factor in some chemical reactions was first made fifty years ago by Hund, very soon after the principles of wave mechanics had been established by de Broglie, Schrodinger and Heisenberg, and similar ideas were put forward during the following thirty years by a number of authors. It was realised from the beginning that such effects would be particularly prominent in reactions involving the movement of protons or hydrogen atoms, and both theoretical and experimental work received a powerful stimulus in the discovery of deuterium in 1932. During the last twenty years theoretical predictions about the tunnel effect have been supported by an increasing body of experimental evidence, derived especially from studies of hydrogen isotope effects. The present book presents an attempt to summarize this evidence and to indicate the main lines of the basic theory. Details of mathematical manipu lation are restricted mainly to Chapter 2 and the Appendices, and many readers may prefer to confine themselves to the results obtained. The main emphasis has been on the kinetics of chemical reactions involving the transfer of protons, hydrogen atoms or hydride ions, although Chapter 6 gives an account of the role of the tunnel effect in molecular spectra, and Chapter 7 makes some mention of tunnelling in solid state phenomena, biological processes and the electrolytic discharge of hydrogen. Only passing references have been made to tunnelling by electrons.
Erscheinungsdatum: 01.01.1980
备用文件名
lgrsnf/D:\HDD4\!genesis\SPR_NEW_2013-12\bok%3A978-1-4899-2891-7.pdf
备用文件名
nexusstc/The Tunnel Effect in Chemistry/06ba0aad38cf4bbcc38846a4cad4ba33.pdf
备用文件名
scihub/10.1007/978-1-4899-2891-7.pdf
备用文件名
zlib/Chemistry/R. P. Bell (auth.)/The Tunnel Effect in Chemistry_2298557.pdf
备选作者
Ronald Percy Bell
备用出版商
International Thomson Computer Press
备用出版商
Springer London, Limited
备用出版商
Cengage Learning EMEA
备用出版商
Chapman and Hall
备用出版商
Thomson Learning
备用版本
United Kingdom and Ireland, United Kingdom
备用版本
United States, United States of America
备用版本
London, New York, United Kingdom, 1980
备用版本
Springer Nature, New York, NY, 2013
备用版本
London, New York, England, 1980
备用版本
Boston, MA, 1980
元数据中的注释
sm22745884
元数据中的注释
{"edition":"1","isbns":["0412213400","148992891X","9780412213403","9781489928917"],"last_page":222,"publisher":"Springer US"}
元数据中的注释
Includes bibliographical references and index.
元数据中的注释
Includes bibliographical references and indexes.
备用描述
Front Matter....Pages i-ix
Physical principles and early history....Pages 1-11
The calculation of permeabilities for one-dimensional barriers....Pages 12-50
The application of tunnel corrections in chemical kinetics....Pages 51-76
The theory of kinetic hydrogen isotope effects....Pages 77-105
Experimental evidence for tunnelling in chemical reactions....Pages 106-144
Tunnelling in molecular spectra....Pages 145-162
A review of the present position....Pages 163-185
Back Matter....Pages 186-222
开源日期
2014-01-18
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