This reference provides collective information about the physical and photophysical changes of supramolecules after encapsulation. It covers luminescent systems involving a range of host molecules such as calixarenes, cyclodextrin, resorcinanene-crowns, pillararenes, cucurbituril, and metallacycles. Chapters also discuss the effect of the macrocyclic environment on the properties of functionalized molecules, including the variations in folding and unfolding patterns. Each chapter is supplemented with detailed references, making this an ideal resource for scholars interested in supramolecular photophysics.

nexusstc/Photophysics of Supramolecular Architectures/1e7568c06a116c61c8f96711e8b97c70.pdf

lgli/sanet.st-Photophysics_of_Supramolecular_Architectures.pdf

lgrsnf/sanet.st-Photophysics_of_Supramolecular_Architectures.pdf

zlib/Biology and other natural sciences/Biophysics/Paulpandian Muthu Mareeswaran, Palaniswamy Suresh, Seenivasan Rajagopal/Photophysics of Supramolecular Architectures_23254218.pdf

Mareeswaran, Paulpandian Muthu;Suresh, Palaniswamy;Rajagopal, Seenivasan;

Singapore, Singapore

producers:
mPDF 5.7

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Cover 1
Title 2
Copyright 3
End User License Agreement 4
Contents 6
Foreword 9
Preface
10
List of Contributors 12
Luminescent Cyclodextrin Systems and Their Applications 13
Bosco Christin Maria Arputham Ashwin1, Venkatesan Sethuraman2 and Paulpandian Muthu Mareeswaran2,* 13
INTRODUCTION 13
HOST-GUEST SYSTEMS 14
LUMINESCENT CYCLODEXTRINS 19
FLUORESCENT SENSORS 25
BIOSENSORS 28
THERAPEUTIC APPLICATION 32
CONCLUSION 35
CONSENT FOR PUBLICATION 35
CONFLICT OF INTEREST 35
ACKNOWLEDGEMENTS 35
REFERENCES 35
Calixarene Based Luminescent Systems 43
Bosco Christin Maria Arputham Ashwin1, Venkatesan Sethuraman2 and Paulpandian Muthu Mareeswaran2,* 43
INTRODUCTION 43
LUMINESCENT HOST-GUEST SYSTEMS 44
Fluorescent Calixarene 45
ION SENSING APPLICATIONS 45
Anion Sensors 55
Solid State Sensor 56
MOLECULAR RECOGNITION 56
LUMINESCENT LANTHANOID CALIXARENE COMPLEXES 58
CONCLUSION 59
CONSENT OF PUBLICATION 60
CONFLICT OF INTEREST 60
ACKNOWLEDGEMENTS 60
REFERENCES 60
Resorcinarene Crowns as Versatile Host Molecules and Their Potential Applications 70
Selvaraj Devi1, Somasundaram Anbu Anjugam Vandarkuzhali2,* and Vairaperumal Tharmaraj3,* 70
INTRODUCTION 70
Synthesis of Resorcinarenes 72
Selective Functionalization of Upper Rim Resorcinarene Crowns 75
Selective functionalization of lower rim resorcinarene crowns 76
APPLICATIONS OF RESORCINARENE CROWNS 77
Chemical Separations 78
Chemical Sensors 79
Catalytic Activity 80
Lithographic Application 81
Antioxidant and Antibacterial Applications 82
CONCLUSION 83
CONSENT OF PUBLICATION 83
CONFLICT OF INTEREST 83
ACKNOWLEDGEMENTS 84
REFERENCES 84
Pillararenes: Younger Luminescent Supramolecular Systems 89
Palaniswamy Suresh1,* and Jeyaraj Belinda Asha1 89
INTRODUCTION 89
Pillararenes 90
Structure of Pillararenes 91
Synthesis of Pillararenes 94
Host-Guest Binding Behaviours of Pillararenes 97
Photophysical Behaviours of Pillararenes 99
Pillararenes Based Luminescence Systems 99
Pillararenes in Sensors Applications 103
Pillararenes in Metal Ions Scavenging 110
Pillararenes Derived Stimuli Luminescent Materials 111
CONCLUSIONS 115
CONSENT OF PUBLICATION 116
CONFLICT OF INTEREST 116
ACKNOWLEDGEMENT 116
REFERENCES 116
Cucurbit[n]urils Based Molecular Recognition with Fluorescence Signalling 123
Liju R.1 and E. Rajkumar1,* 123
INTRODUCTION 123
Cucurbituril CB[n] 125
Structural Features of CB[n]s 125
Physical Properties of CB[n]s 126
CB[n] Based Sensors 128
Detection Mechanism 129
Direct Binding Assay 129
Associative Binding Assay 130
Indicator Displacement Assay (IDA) 131
Detection of Metal Ions 133
Detection of Amino Acids and Peptide Molecules 135
Detection of Biomolecules 137
Detection of Organic Compound 138
Cucurbit[n]urils in Imaging and in Photodynamic Therapy 140
CONCLUSION 143
CONSENT OF PUBLICATION 143
CONFLICT OF INTEREST 144
ACKNOWLEDGEMENT 144
REFERENCES 144
Rhenium(I)-Based Metallacycles for Sensing Applications 149
Murugesan Velayudham1,* and Pounraj Thanasekaran2,* 149
INTRODUCTION 149
Rhenium(I)-Based Metallacycles 152
Binuclear Re(I) Complex 153
Trinuclear Re(I) Complex 161
Tetranuclear Re(I) Complex 162
Hexanuclear Re(I) Complex 182
Octanuclear Re(I) Complex 185
CONCLUSIONS 186
CONSENT FOR PUBLICATION 187
CONFLICT OF INTEREST 188
ACKNOWLEDGEMENTS 188
REFERENCES 188
Recent Developments in the Dynamics of Fluorescently Labelled Macromolecules 193
Kandhasamy Durai Murugan1,*, Pandi Muthirulan2 and Vijayanand Chandrasekaran3 193
INTRODUCTION 193
POLY(ACRYLIC ACIDS) – STRUCTURAL TRANSITION AND DYNAMICS 195
PHOTOPHYSICS OF FLUOROPHORES IN POLYELECTROLYTES 197
PHOTOPHYSICS OF EXCITED STATE FLUOROPHORES 197
IMPORTANCE OF PHOTOPHYSICS AND PHOTOCHEMISTRY OF POLYMERIC MATERIALS 198
PHOTOPHYSICS AND CONFORMATIONAL DYNAMICS OF POLYELECTROLYTES 200
STEADY STATE FLUORESCENCE STUDIES AND FLUORESCENCE QUENCHING 201
EXCITED STATE ENERGY AND ELECTRON TRANSFER 202
EXCIMER AND EXCIPLEX FORMATION 204
TIME–RESOLVED FLUORESCENCE STUDIES AND SOLVATION DYNAMICS 205
POLYMER COMPLEXES 210
INTERPOLYMER COMPLEXES 211
HYDROGEN BONDED INTERPOLYMER COMPLEXES 212
CONCLUSION 214
CONSENT OF PUBLICATION 214
CONFLICT OF INTEREST 214
ACKNOWLEDGMENT 215
REFERENCES 215
Subject Index
226
Back Cover
237

2022-10-11