vi the information collected and discussed in this volume may help toward the achievement of such an objective. I should like to express my debt of gratitude to the authors who have contributed to this volume. Editing a work of this nature can strain long established personal relationships and I thank my various colleagues for bearing with me and responding (sooner or later) to one or several letters or telephone calls. My special thanks once again go to Mrs. Joyce Johnson, who bore the main brunt of this seemingly endless correspondence and without whose help the editorial and referencing work would have taken several years. F. FRANKS Biophysics Division Unilever Research Laboratory Colworth/ Welwyn Colworth House, Sharnbrook, Bedford January, 1973 Contents Contents of Volume 1 ............................. . . . . . .. . . .. xv Contents of Volume 3 ........................ '. . . . . . . . . . . . xvi . . . . Contents of Volume 4 . . . . . . . . . . . . . . . . . . . . . . . . .. . . . xvii . . . . . . . . . . . Chapter 1 The Solvent Properties of Water F. Franks 1. Water, the Universal Solvent-the Study of Aqueous Solutions 2. Aqueous Solutions of Nonelectrolytes ................. . 5 2.1. Apolar Solutes ................................. . 6 2.2. Polar Solutes .................................. . 19 2.3. Ionic Solutes Containing Alkyl Residues-"Apolar Electrolytes" ................................... . 38 3. Aqueous Solutions of Electrolytes .................... . 42 3.1. Single Ion Properties ............................ . 42 3.2. Ion-Water Interactions ......................... . 43 3.3. Interionic Effects ............................... . 47 4. Complex Aqueous Mixtures 48 Chapter 2 Water in Stoichiometric Hydrates M. Falk and O. Knop 1. Introduction. . . . . .. . . . . . . . . . . . . . . . . . . . . . . 55 . . . . . . . . . . . . . 2. Symmetry and Types of Environment of the H0 Molecule 2 in Crystals .......................................... 57 vii Contents viii 2.1. Site Symmetry. . . . . . . . . . . . . . . . . . . . . . . . . 57 . . . . . . . . . .
Erscheinungsdatum: 06.02.2013

lgrsnf/A:\Springer\bok%3A978-1-4757-6958-6.pdf

nexusstc/Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes/4bb0ed12447dc8bff15da6515bfe3201.pdf

zlib/Chemistry/F. Franks (auth.), Felix Franks (eds.)/Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes_2250616.pdf

Springer US : Imprint: Springer

Springer-Verlag

Plenum Press

Softcover reprint of the original 1st ed. 1973, 2013

Water, a comprehensive treatise, Boston, MA, 1973

Water, a comprehensive treatise, New York, 1973

United States, United States of America

Springer Nature, New York, NY, 2013

uuuu

lg1081652

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Vi the information collected and discussed in this volume may help toward the achievement of such an objective. I should like to express my debt of gratitude to the authors who have contributed to this volume. Editing a work of this nature can strain longƯ established personal relationships and I thank my various colleagues for bearing with me and responding (sooner or later) to one or several letters or telephone calls. My special thanks once again go to Mrs. Joyce Johnson, who bore the main brunt of this seemingly endless correspondence and without whose help the editorial and referencing work would have taken several years. F. FRANKS Biophysics Division Unilever Research Laboratory Colworth/ Welwyn Colworth House, Sharnbrook, Bedford January, 1973 Contents Contents of Volume 1 ... . . .. . . .. xv Contents of Volume 3 ... '. ... ... . xvi ... Contents of Volume 4 ... ... ... ... .. ... xvii ... ... . Chapter 1 The Solvent Properties of Water F. Franks 1. Water, the Universal Solvent-the Study of Aqueous Solutions 2. Aqueous Solutions of Nonelectrolytes ... 5 2.1. Apolar Solutes ... 6 2.2. Polar Solutes ... 19 2.3. Ionic Solutes Containing Alkyl Residues-"Apolar Electrolytes" ... 38 3. Aqueous Solutions of Electrolytes ... 42 3.1. Single Ion Properties ... 42 3.2. Ion-Water Interactions ... 43 3.3. Interionic Effects ... 47 4. Complex Aqueous Mixtures 48 Chapter 2 Water in Stoichiometric Hydrates M. Falk and O. Knop 1. Introduction. ... ... ... ... ... 55 ... ... . 2. Symmetry and Types of Environment of the H0 Molecule 2 in Crystals ... 57 vii Contents viii 2.1. Site Symmetry. ... ... ... ... 57 ... ..

Front Matter....Pages i-xix
The Solvent Properties of Water....Pages 1-54
Water in Stoichiometric Hydrates....Pages 55-113
Clathrate Hydrates....Pages 115-234
Infrared Studies of Hydrogen Bonding in Pure Liquids and Solutions....Pages 235-321
Thermodynamic Properties....Pages 323-380
Phase Behavior of Aqueous Solutions at High Pressures....Pages 381-404
Dielectric Properties....Pages 405-458
Spectroscopic Properties....Pages 459-494
Acoustic Properties....Pages 495-528
NMR Spectroscopic Studies....Pages 529-584
Molecular Theories and Models of Water and of Dilute Aqueous Solutions....Pages 585-624
Back Matter....Pages 625-684

2013-12-12