The book provides a complete overview on inorganic pigments and their use in dye industry. Each chapter introduces a certain class of pigment in respect of fundamentals, manufacture, properties and toxicology and thus being very valuable for paint chemists and materials specialists. The readers will benefit from a concise and well-structured text, numerous examples and a set of test questions in the end of each chapter.
- Newly added: history of pigments and colorimetry and color formulation.
- Each chapter has a uniform structure based on a certain type of pigment.
- A set of questions is provided in the end of each chapter to test the understanding of the content.

lgli/Pfaff G. Inorganic Pigments, 2-nd Ed._2023.pdf

lgrsnf/Pfaff G. Inorganic Pigments, 2-nd Ed._2023.pdf

zlib/no-category/Pfaff G./Inorganic Pigments_25795063.pdf

Pfaff, Gerhard

düsseldorf university press. in Walter de Gruyter GmbH

de Gruyter, Walter, GmbH

de Gruyter GmbH, Walter

De Gruyter, Berlin/Boston, 2023

Germany, Germany

S.l, 2023

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Cover
Half Title
Also of interest
Inorganic Pigments
Copyright
Preface to the second edition
Preface to the first edition
Contents
1. Fundamentals, general aspects, color, application
1.1 Definitions and classification
1.2 History and economic aspects
1.3 Uses
1.4 General chemical and physical properties
1.5 Color properties of inorganic pigments
1.5.1 Fundamental aspects
1.5.1.1 Mie theory
1.5.1.2 Theory of multiple scattering
1.5.1.3 Kubelka–Munk theory
1.5.1.4 Colorimetry
1.5.2 Color and color vision
1.5.3 Origin of color for colored pigments
1.5.4 Optical parameters
1.6 Application technical behavior
1.6.1 Pigment–binder interaction
1.6.2 Stability against light, weather, heat, and chemicals
1.7 Conclusions
Bibliography
2. General methods of manufacture
2.1 Mechanical preparation processes
2.1.1 Crushing and grinding
2.1.2 Classifying
2.1.3 Blending and conveying
2.2 Precipitation reactions
2.3 Calcination processes
2.4 Other methods
2.4.1 Flux crystallization processes
2.4.2 Hydrothermal reactions
2.4.3 Gas-phase reactions
2.5 Conclusions
Bibliography
3. White pigments
3.1 Introduction
3.2 Titanium dioxide pigments
3.2.1 Fundamentals and properties
3.2.2 Production of titanium dioxide pigments
3.2.2.1 Raw materials
3.2.2.1.1 Natural raw materials
3.2.2.1.2 Synthetic raw materials
3.2.2.2 The sulfate process
3.2.2.3 The chloride process
3.2.2.4 Inorganic and organic surface treatment
3.2.2.5 Waste management
3.2.3 Pigment properties and uses
3.2.4 Toxicology and occupational health
3.3 Zinc sulfide pigments
3.3.1 Fundamentals and properties
3.3.2 Production of zinc sulfide pigments
3.3.2.1 Raw materials
3.3.2.2 Pure zinc sulfide pigments
3.3.2.3 Lithopone
3.3.3 Pigment properties and uses
3.3.4 Toxicology and occupational health
3.4 Zinc oxide pigments
3.4.1 Fundamentals and properties
3.4.2 Production of zinc oxide pigments
3.4.2.1 Raw materials
3.4.2.2 Direct process (American process)
3.4.2.3 Indirect process (French process)
3.4.2.4 Precipitation process
3.4.2.5 Surface treatment
3.4.3 Pigment properties and uses
3.4.4 Toxicology and occupational health
3.5 Other white pigments
3.5.1 Basic lead carbonate (white lead)
3.5.2 Antimony(III) oxide (antimony white)
3.6 Conclusions
Bibliography
4. Colored pigments
4.1 Introduction
4.2 Iron oxide pigments
4.2.1 Fundamentals and properties
4.2.2 Natural iron oxide pigments
4.2.3 Synthetic iron oxide pigments
4.2.4 Production of iron oxide pigments
4.2.4.1 Solid-state processes
4.2.4.2 Precipitation processes
4.2.4.3 The Laux process
4.2.4.4 Other production processes
4.2.5 Pigment properties and uses
4.2.6 Toxicology and occupational health
4.3 Chromium oxide pigments
4.3.1 Fundamentals and properties
4.3.2 Production of chromium oxide pigments
4.3.2.1 Reduction of alkali dichromates
4.3.2.2 Reduction of ammonium dichromate
4.3.2.3 Other production processes
4.3.3 Pigment properties and uses
4.3.4 Toxicology and occupational health
4.4 Mixed metal oxide pigments
4.4.1 Fundamentals and properties
4.4.2 Production of MMO pigments
4.4.2.1 Rutile MMO pigments
4.4.2.2 Spinel MMO pigments
4.4.2.3 Zirconium silicate pigments (ceramic colors)
4.4.3 Pigment properties and uses
4.4.4 Toxicology and occupational health
4.5 Chromate and molybdate pigments
4.5.1 Fundamentals and properties
4.5.2 Production of chromate and molybdate pigments
4.5.3 Pigment properties and uses
4.5.4 Toxicology and occupational health
4.6 Bismuth vanadate pigments
4.6.1 Fundamentals and properties
4.6.2 Production of bismuth vanadate pigments
4.6.3 Pigment properties and uses
4.6.4 Toxicology and occupational health
4.7 Ultramarine pigments
4.7.1 Fundamentals and properties
4.7.2 Production of ultramarine pigments
4.7.3 Pigment properties and uses
4.7.4 Toxicology and occupational health
4.8 Iron blue pigments
4.8.1 Fundamentals and properties
4.8.2 Production of iron blue pigments
4.8.3 Pigment properties and uses
4.8.4 Toxicology and occupational health
4.9 Cadmium sulfide/selenide pigments
4.9.1 Fundamentals and properties
4.9.2 Production of cadmium sulfide/selenide pigments
4.9.3 Pigment properties and uses
4.9.4 Toxicology and occupational health
4.10 Cerium sulfide pigments
4.10.1 Fundamentals and properties
4.10.2 Production of cerium sulfide pigments
4.10.3 Pigment properties and uses
4.10.4 Toxicology and occupational health
4.11 Oxonitride pigments
4.11.1 Fundamentals and properties
4.11.2 Production of oxonitride pigments
4.11.3 Pigment properties and uses
4.11.4 Toxicology and occupational health
4.12 Yttrium indium manganese oxide pigments
4.12.1 Fundamentals and properties
4.12.2 Production of yttrium indium manganese oxide pigments
4.12.3 Pigment properties and uses
4.12.4 Toxicology and occupational health
4.13 New approaches for the development of inorganic colored pigments
4.13.1 Intention for new developments
4.13.2 Blue pigments
4.13.3 Violet pigments
4.13.4 Green pigments
4.13.5 Yellow pigments
4.13.6 Orange pigments
4.14 Conclusions
Bibliography
5. Black pigments (carbon black)
5.1 Fundamentals and properties
5.2 Production of carbon black pigments
5.2.1 Raw materials
5.2.2 Furnace black process
5.2.3 Channel black and gas black processes
5.2.4 Lamp black process
5.2.5 Thermal black process
5.2.6 Acetylene black process
5.2.7 Other production processes
5.2.8 Oxidative aftertreatment
5.2.9 Pelletizing of carbon black
5.3 Pigment properties and uses
5.4 Toxicology and occupational health
5.5 Conclusions
Bibliography
6. Ceramic colors
6.1 Fundamentals and properties
6.2 Types and applications of ceramic colors
6.2.1 Cadmium sulfide and sulfoselenides
6.2.2 Metals
6.2.3 Metal oxides
6.2.4 Mixed metal oxides and silicates
6.2.5 Zirconia-based compositions
6.2.6 Zircon-based compositions
6.3 Toxicology and occupational health
6.4 Conclusions
Bibliography
7. Transparent pigments
7.1 Fundamentals and properties
7.2 Transparent iron oxides
7.3 Transparent cobalt blue
7.4 Transparent iron blue
7.5 Transparent titanium dioxide
7.6 Transparent zinc oxide
7.7 Toxicology and occupational health
7.8 Conclusions
Bibliography
8. Effect pigments
8.1 Fundamentals and properties
8.2 Metal effect pigments
8.2.1 Optical properties
8.2.2 Production of metal effect pigments
8.2.2.1 Aluminum pigments
8.2.2.2 Gold bronze pigments
8.2.2.3 Zinc pigments
8.2.2.4 Colored aluminum pigments
8.2.3 Pigment properties and uses
8.2.4 Toxicology and occupational health
8.3 Special effect pigments
8.3.1 Optical principles of special effect pigments
8.3.2 Substrate-free pigments
8.3.2.1 Natural fish silver
8.3.2.2 Basic lead carbonate
8.3.2.3 Bismuth oxychloride
8.3.2.4 Micaceous iron oxide
8.3.2.5 Titanium dioxide flakes
8.3.3 Pigments based on the layer-substrate principle
8.3.3.1 Metal oxide mica pigments
8.3.3.1.1 Fundamentals
8.3.3.1.2 Production of metal oxide mica pigments
8.3.3.1.3 Functional metal oxide mica pigments
8.3.3.2 Effect pigments based on silica flakes
8.3.3.3 Effect pigments based on alumina flakes
8.3.3.4 Effect pigments based on borosilicate flakes
8.3.3.5 Comparison of different effect pigments based on the layer-substrate principle
8.3.4 Pigment properties and uses
8.3.5 Toxicology and occupational health
8.4 Conclusions
Bibliography
9. Functional pigments
9.1 Magnetic pigments
9.1.1 Fundamentals and general properties
9.1.2 Production, special properties, and uses of magnetic pigments
9.1.2.1 Iron oxide pigments
9.1.2.2 Cobalt-containing iron oxide pigments
9.1.2.3 Metallic iron pigments
9.1.2.4 Chromium dioxide pigments
9.1.2.5 Barium ferrite pigments
9.1.2.6 Toner pigments
9.1.3 Toxicology and occupational health
9.2 Anticorrosive pigments
9.2.2 Production and special properties of anticorrosive pigments
9.2.2.1 Lead-containing and chromate pigments
9.2.2.2 Phosphate pigments
9.2.2.3 Other phosphorous-containing pigments
9.2.2.4 Borate pigments
9.2.2.5 Molybdate pigments
9.2.2.6 Ion exchange pigments
9.2.2.7 Titanium dioxide-based pigments
9.2.2.8 Inorganic organic hybrid pigments
9.2.2.9 Zinc cyanamide pigments
9.2.2.10 Micaceous iron oxide pigments
9.2.2.11 Metallic zinc pigments
9.2.2.12 Graphene-based composite materials
9.2.1 Fundamentals and general properties
9.2.3 Specification of corrosion protection standards
9.2.4 Toxicology and occupational health
9.3 Conclusions
Bibliography
10. Luminescent pigments
10.1 Fundamentals and properties
10.2 Luminescence mechanisms
10.3 Excitation mechanisms
10.4 Production of luminescent pigments
10.5 Pigment properties and uses
10.6 Toxicology and occupational health
10.7 Conclusions
Bibliography
11. Fillers
11.1 Fundamentals and properties
11.2 Production of fillers
11.2.1 Natural fillers
11.2.2 Synthetic fillers
11.3 Filler properties and uses
11.4 Toxicology and occupational health
11.5 Conclusions
Bibliography
12. Application systems for pigments
12.1 Coatings
12.2 Plastics
12.3 Printing inks
12.4 Cosmetic formulations
12.5 Building materials
12.6 Conclusions
Bibliography
Answers to the study questions
Chapter 1: Fundamentals, general aspects, color, application
Chapter 2: General methods of manufacture
Chapter 3: White pigments
Chapter 4: Colored pigments
Chapter 5: Black pigments (carbon black)
Chapter 6: Ceramic colors
Chapter 7: Transparent pigments
Chapter 8: Effect pigments
Chapter 9: Functional pigments
Chapter 10: Luminescent pigments
Chapter 11: Fillers
Chapter 12: Application systems for pigments
Index

The book provides a complete overview on inorganic pigments and their use in coatings, plastics, printing, cosmetic, and construction industries. Each chapter introduces a certain class of pigment in respect of fundamentals, manufacture, properties and toxicology and thus being very valuable for color chemists, materials scientists and specialists for pigment applications. The readers will benefit from a concise and well-structured text, numerous examples and figures, and a variety of questions for self-control.

2023-08-17