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Introduction to Coordination Chemistry 🔍
Lawrance, Geoffrey A. John Wiley & Sons, Incorporated, Inorganic Chemistry: A Textbook Series, 2010
英语 [en] · PDF · 4.5MB · 2010 · 📘 非小说类图书 · 🚀/lgli/lgrs/nexusstc/upload/zlib · Save
描述
At the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met ‘naked’ – they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and accessible style Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography. Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers.
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lgli/Ch_Chemistry/Lawrance G.A. Introduction to Coordination Chemistry (Wiley, 2010)(ISBN 0470519312)(O)(307s)_Ch_.pdf
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lgrsnf/Ch_Chemistry/Lawrance G.A. Introduction to Coordination Chemistry (Wiley, 2010)(ISBN 0470519312)(O)(307s)_Ch_.pdf
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nexusstc/Introduction to Coordination Chemistry/bfc5f0b5865ef6d3f0387230642ac4eb.pdf
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zlib/Chemistry/Lawrance G.A./Introduction to Coordination Chemistry_1022633.pdf
备选作者
Geoffrey A. Lawrance
备用出版商
Spectrum Publications
备用出版商
Halsted Press
备用版本
Inorganic chemistry, Inorganic chemistry (John Wiley & Sons), Chichester, U.K, England, 2010
备用版本
Wiley Blackwell Higher Education, Chichester, U.K., 2010
备用版本
United States, United States of America
备用版本
Chichester, West Sussex, England, 2010
备用版本
1, 2010
元数据中的注释
Kolxo3 -- 2011
元数据中的注释
lg598461
元数据中的注释
producers:
Acrobat Distiller 6.0.1 (Windows)
元数据中的注释
{"isbns":["0470519312","9780470519318"],"last_page":307,"publisher":"Wiley","series":"Inorganic Chemistry: A Textbook Series"}
元数据中的注释
Includes bibliographical references and index.
备用描述
Introduction to Coordination Chemistry 4
Contents 8
Preface 12
Preamble 14
1 The Central Atom 18
1.1 Key Concepts in Coordination Chemistry 18
1.2 A Who’s Who of Metal Ions 21
1.2.1 Commoners and ‘Uncommoners’ 22
1.2.2 Redefining Commoners 24
1.3 Metals in Molecules 26
1.3.1 Metals in the Natural World 27
1.3.2 Metals in Contrived Environments 28
1.3.3 Natural or Made-to-Measure Complexes 29
1.4 The Road Ahead 30
Concept Keys 31
Further Reading 31
2 Ligands 32
2.1 Membership: Being a Ligand 32
2.1.1 What Makes a Ligand? 32
2.1.2 Making Attachments – Coordination 33
2.1.3 Putting the Bite on Metals – Chelation 34
2.1.4 Do I Look Big on That? – Chelate Ring Size 39
2.1.5 Different Tribes – Donor Group Variation 40
2.1.6 Ligands with More Bite – Denticity 41
2.2 Monodentate Ligands – The Simple Type 43
2.2.1 Basic Binders 43
2.2.2 Amines Ain’t Ammines – Ligand Families 44
2.2.3 Meeting More Metals – Bridging Ligands 44
2.3 Greed is Good – Polydentate Ligands 46
2.3.1 The Simple Chelate 46
2.3.2 More Teeth, Stronger Bite – Polydentates 48
2.3.3 Many-Armed Monsters – Introducing Ligand Shape 49
2.4 Polynucleating Species – Molecular Bigamists 50
2.4.1 When One is Not Enough 50
2.4.2 Vive la Difference – Mixed-metal Complexation 51
2.4.3 Supersized – Binding to Macromolecules 53
2.5 A Separate Race – Organometallic Species 53
Concept Keys 55
Further Reading 56
3 Complexes 58
3.1 The Central Metal Ion 58
3.2 Metal–Ligand Marriage 59
3.2.1 The Coordinate Bond 59
3.2.2 The Foundation of Coordination Chemistry 59
3.2.3 Complex Shape – Not Just Any Which Way 62
3.3 Holding On – The Nature of Bonding in Metal Complexes 66
3.3.1 An Ionic Bonding Model – Introducing Crystal Field Theory 70
3.3.2 A Covalent Bonding Model – Embracing Molecular Orbital Theory 74
3.3.3 Ligand Field Theory – Making Compromises 79
3.3.4 Bonding Models Extended 80
3.4 Coupling – Polymetallic Complexes 90
3.5 Making Choices 92
3.5.1 Selectivity – Of all the Molecules in all the World, Why This One? 92
3.5.2 Preferences – Do You Like What I Like? 92
3.5.3 Complex Lifetimes – Together, Forever? 94
3.6 Complexation Consequences 97
Concept Keys 98
Further Reading 99
4 Shape 100
4.1 Getting in Shape 100
4.2 Forms of Complex Life – Coordination Number and Shape 103
4.2.1 One Coordination (ML) 103
4.2.2 Two Coordination (ML2) 104
4.2.3 Three Coordination (ML3) 105
4.2.4 Four Coordination (ML4) 106
4.2.5 Five Coordination (ML5) 110
4.2.6 Six Coordination (ML6) 113
4.2.7 Higher Coordination Numbers (ML7 to ML9) 115
4.3 Influencing Shape 118
4.3.1 Metallic Genetics – Metal Ion Influences 118
4.3.2 Moulding a Relationship – Ligand Influences 120
4.3.3 Chameleon Complexes 122
4.4 Isomerism – Real 3D Effects 122
4.4.1 Introducing Stereoisomers 123
4.4.2 Constitutional (Structural) Isomerism 123
4.4.3 Stereoisomerism: in Place – Positional Isomers; in Space – Optical Isomers 126
4.4.4 What’s Best? – Isomer Preferences 130
4.5 Sophisticated Shapes 132
4.5.1 Compounds of Polydentate Ligands 133
4.5.2 Encapsulation Compounds 134
4.5.3 Host–Guest Molecular Assemblies 138
4.6 Defining Shape 140
Concept Keys 140
Further Reading 141
5 Stability 142
5.1 The Makings of a Stable Relationship 142
5.1.1 Bedded Down – Thermodynamic Stability 142
5.1.2 Factors Influencing Stability of Metal Complexes 144
5.1.3 Overall Stability Constants 155
5.1.4 Undergoing Change – Kinetic Stability 158
5.2 Complexation – Will It Last? 160
5.2.1 Thermodynamic and Kinetic Stability 160
5.2.2 Kinetic Rate Constants 161
5.2.3 Lability and Inertness in Octahedral Complexes 162
5.3 Reactions 163
5.3.1 A New Partner – Substitution 164
5.3.2 A New Body – Stereochemical Change 172
5.3.3 A New Face – Oxidation–Reduction 177
5.3.4 A New Suit – Ligand-centred Reactions 186
Concept Keys 187
Further Reading 187
6 Synthesis 190
6.1 Molecular Creation – Ways to Make Complexes 190
6.2 Core Metal Chemistry – Periodic Table Influences 190
6.2.1 s Block: Alkali and Alkaline Earth Metals 190
6.2.2 p Block: Main Group Metals 191
6.2.3 d Block: Transition Metals 192
6.2.4 f Block: Inner Transition Metals (Lanthanoids and Actinoids) 193
6.2.5 Beyond Natural Elements 195
6.3 Reactions Involving the Coordination Shell 196
6.3.1 Ligand Substitution Reactions in Aqueous Solution 196
6.3.2 Substitution Reactions in Nonaqueous Solvents 201
6.3.3 Substitution Reactions without using a Solvent 203
6.3.4 Chiral Complexes 206
6.3.5 Catalysed Reactions 207
6.4 Reactions Involving the Metal Oxidation State 207
6.5 Reactions Involving Coordinated Ligands 211
6.5.1 Metal-directed Reactions 211
6.5.2 Reactions of Coordinated Ligands 214
6.6 Organometallic Synthesis 220
Concept Keys 223
Further Reading 224
7 Properties 226
7.1 Finding Ways to Make Complexes Talk – Investigative Methods 226
7.2 Getting Physical – Methods and Outcomes 227
7.3 Probing the Life of Complexes – Using Physical Methods 231
7.3.1 Peak Performance – Illustrating Selected Physical Methods 233
7.3.2 Pretty in Red? – Colour and the Spectrochemical Series 237
7.3.3 A Magnetic Personality? – Paramagnetism and Diamagnetism 240
7.3.4 Ligand Field Stabilization 242
Concept Keys 244
Further Reading 244
8 A Complex Life 246
8.1 Life’s a Metal Ion 246
8.1.1 Biological Ligands 246
8.1.2 Metal Ions in Biology 248
8.1.3 Classes of Metallobiomolecules 250
8.2 Metalloproteins and Metalloenzymes 250
8.2.1 Iron-containing Biomolecules 251
8.2.2 Copper-containing Biomolecules 257
8.2.3 Zinc-containing Biomolecules 259
8.2.4 Other Metal-containing Biomolecules 260
8.2.5 Mixed-Metal Proteins 261
8.3 Doing What Comes Unnaturally – Synthetic Biomolecules 262
8.4 A Laboratory-free Approach – In Silico Prediction 264
Concept Keys 266
Further Reading 267
9 Complexes and Commerce 268
9.1 Kill or Cure? – Complexes as Drugs 268
9.1.1 Introducing Metallodrugs 269
9.1.2 Anticancer Drugs 269
9.1.3 Other Metallodrugs 272
9.2 How Much? – Analysing with Complexes 273
9.2.1 Fluoroimmunoassay 273
9.2.2 Fluoroionophores 275
9.3 Profiting from Complexation 276
9.3.1 Metal Extraction 276
9.3.2 Industrial Roles for Ligands and Coordination Complexes 278
9.4 Being Green 280
9.4.1 Complexation in Remediation 281
9.4.2 Better Ways to Synthesize Fine Organic Chemicals 281
9.5 Complex Futures 281
9.5.1 Taking Stock 282
9.5.2 Crystal Ball Gazing 282
Concept Keys 283
Further Reading 283
Appendix A: Nomenclature 286
Appendix B: Molecular Symmetry: The Point Group 294
Index 300
备用描述
Introduction to Coordination Chemistry......Page 4
Contents......Page 8
Preface......Page 12
Preamble......Page 14
1.1 Key Concepts in Coordination Chemistry......Page 18
1.2 A Who’s Who of Metal Ions......Page 21
1.2.1 Commoners and ‘Uncommoners’......Page 22
1.2.2 Redefining Commoners......Page 24
1.3 Metals in Molecules......Page 26
1.3.1 Metals in the Natural World......Page 27
1.3.2 Metals in Contrived Environments......Page 28
1.3.3 Natural or Made-to-Measure Complexes......Page 29
1.4 The Road Ahead......Page 30
Further Reading......Page 31
2.1.1 What Makes a Ligand?......Page 32
2.1.2 Making Attachments – Coordination......Page 33
2.1.3 Putting the Bite on Metals – Chelation......Page 34
2.1.4 Do I Look Big on That? – Chelate Ring Size......Page 39
2.1.5 Different Tribes – Donor Group Variation......Page 40
2.1.6 Ligands with More Bite – Denticity......Page 41
2.2.1 Basic Binders......Page 43
2.2.3 Meeting More Metals – Bridging Ligands......Page 44
2.3.1 The Simple Chelate......Page 46
2.3.2 More Teeth, Stronger Bite – Polydentates......Page 48
2.3.3 Many-Armed Monsters – Introducing Ligand Shape......Page 49
2.4.1 When One is Not Enough......Page 50
2.4.2 Vive la Difference – Mixed-metal Complexation......Page 51
2.5 A Separate Race – Organometallic Species......Page 53
Concept Keys......Page 55
Further Reading......Page 56
3.1 The Central Metal Ion......Page 58
3.2.2 The Foundation of Coordination Chemistry......Page 59
3.2.3 Complex Shape – Not Just Any Which Way......Page 62
3.3 Holding On – The Nature of Bonding in Metal Complexes......Page 66
3.3.1 An Ionic Bonding Model – Introducing Crystal Field Theory......Page 70
3.3.2 A Covalent Bonding Model – Embracing Molecular Orbital Theory......Page 74
3.3.3 Ligand Field Theory – Making Compromises......Page 79
3.3.4 Bonding Models Extended......Page 80
3.4 Coupling – Polymetallic Complexes......Page 90
3.5.2 Preferences – Do You Like What I Like?......Page 92
3.5.3 Complex Lifetimes – Together, Forever?......Page 94
3.6 Complexation Consequences......Page 97
Concept Keys......Page 98
Further Reading......Page 99
4.1 Getting in Shape......Page 100
4.2.1 One Coordination (ML)......Page 103
4.2.2 Two Coordination (ML2)......Page 104
4.2.3 Three Coordination (ML3)......Page 105
4.2.4 Four Coordination (ML4)......Page 106
4.2.5 Five Coordination (ML5)......Page 110
4.2.6 Six Coordination (ML6)......Page 113
4.2.7 Higher Coordination Numbers (ML7 to ML9)......Page 115
4.3.1 Metallic Genetics – Metal Ion Influences......Page 118
4.3.2 Moulding a Relationship – Ligand Influences......Page 120
4.4 Isomerism – Real 3D Effects......Page 122
4.4.2 Constitutional (Structural) Isomerism......Page 123
4.4.3 Stereoisomerism: in Place – Positional Isomers; in Space – Optical Isomers......Page 126
4.4.4 What’s Best? – Isomer Preferences......Page 130
4.5 Sophisticated Shapes......Page 132
4.5.1 Compounds of Polydentate Ligands......Page 133
4.5.2 Encapsulation Compounds......Page 134
4.5.3 Host–Guest Molecular Assemblies......Page 138
Concept Keys......Page 140
Further Reading......Page 141
5.1.1 Bedded Down – Thermodynamic Stability......Page 142
5.1.2 Factors Influencing Stability of Metal Complexes......Page 144
5.1.3 Overall Stability Constants......Page 155
5.1.4 Undergoing Change – Kinetic Stability......Page 158
5.2.1 Thermodynamic and Kinetic Stability......Page 160
5.2.2 Kinetic Rate Constants......Page 161
5.2.3 Lability and Inertness in Octahedral Complexes......Page 162
5.3 Reactions......Page 163
5.3.1 A New Partner – Substitution......Page 164
5.3.2 A New Body – Stereochemical Change......Page 172
5.3.3 A New Face – Oxidation–Reduction......Page 177
5.3.4 A New Suit – Ligand-centred Reactions......Page 186
Further Reading......Page 187
6.2.1 s Block: Alkali and Alkaline Earth Metals......Page 190
6.2.2 p Block: Main Group Metals......Page 191
6.2.3 d Block: Transition Metals......Page 192
6.2.4 f Block: Inner Transition Metals (Lanthanoids and Actinoids)......Page 193
6.2.5 Beyond Natural Elements......Page 195
6.3.1 Ligand Substitution Reactions in Aqueous Solution......Page 196
6.3.2 Substitution Reactions in Nonaqueous Solvents......Page 201
6.3.3 Substitution Reactions without using a Solvent......Page 203
6.3.4 Chiral Complexes......Page 206
6.4 Reactions Involving the Metal Oxidation State......Page 207
6.5.1 Metal-directed Reactions......Page 211
6.5.2 Reactions of Coordinated Ligands......Page 214
6.6 Organometallic Synthesis......Page 220
Concept Keys......Page 223
Further Reading......Page 224
7.1 Finding Ways to Make Complexes Talk – Investigative Methods......Page 226
7.2 Getting Physical – Methods and Outcomes......Page 227
7.3 Probing the Life of Complexes – Using Physical Methods......Page 231
7.3.1 Peak Performance – Illustrating Selected Physical Methods......Page 233
7.3.2 Pretty in Red? – Colour and the Spectrochemical Series......Page 237
7.3.3 A Magnetic Personality? – Paramagnetism and Diamagnetism......Page 240
7.3.4 Ligand Field Stabilization......Page 242
Further Reading......Page 244
8.1.1 Biological Ligands......Page 246
8.1.2 Metal Ions in Biology......Page 248
8.2 Metalloproteins and Metalloenzymes......Page 250
8.2.1 Iron-containing Biomolecules......Page 251
8.2.2 Copper-containing Biomolecules......Page 257
8.2.3 Zinc-containing Biomolecules......Page 259
8.2.4 Other Metal-containing Biomolecules......Page 260
8.2.5 Mixed-Metal Proteins......Page 261
8.3 Doing What Comes Unnaturally – Synthetic Biomolecules......Page 262
8.4 A Laboratory-free Approach – In Silico Prediction......Page 264
Concept Keys......Page 266
Further Reading......Page 267
9.1 Kill or Cure? – Complexes as Drugs......Page 268
9.1.2 Anticancer Drugs......Page 269
9.1.3 Other Metallodrugs......Page 272
9.2.1 Fluoroimmunoassay......Page 273
9.2.2 Fluoroionophores......Page 275
9.3.1 Metal Extraction......Page 276
9.3.2 Industrial Roles for Ligands and Coordination Complexes......Page 278
9.4 Being Green......Page 280
9.5 Complex Futures......Page 281
9.5.2 Crystal Ball Gazing......Page 282
Further Reading......Page 283
Appendix A: Nomenclature......Page 286
Appendix B: Molecular Symmetry: The Point Group......Page 294
Index......Page 300
备用描述
"Written in a highly readable, descriptive and accessible style, Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography." "Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers."--Jacket
备用描述
Introduction to Coordination Chemistry examines and explains how metals and molecules that bind as ligands interact, and the consequences of this assembly process. This book describes the chemical and physical properties and behavior of the complex assemblies that form, and applications that may arise as a result of these properties. Coordination complexes are an important but often hidden part of our world?even part of us?and what they do is probed in this book. This book distills the essence of this topic for undergraduate students and for research scientists
开源日期
2011-07-22
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