Recent studies on the molecular mechanism of water photooxidation (or oxygen photoevolution) reaction on TiO2 and related metal oxides or oxynitrides are reviewed. It is shown that a lot of experimental and theoretical studies give definite support to our recently proposed new mechanism, called “nucleophilic attack of H2O” or “Lewis acid-base” mechanism. The new mechanism has the prominent features that it possesses energetic and kinetics different from the conventional electron-transfer mechanism and can explain water photooxidation reaction on visible-light responsive metal oxides or oxynitrides, contrary to the conventional one. The result indicates that the new mechanism is useful for searching for new efficient visible-light responsive materials for solar water splitting.

lgrsnf/G:\!genesis\1\trans tech\Solid State Phenomena Volume 162 Solid State C.pdf

nexusstc/Molecular Mechanism of Water Oxidation Reaction at Photo-Irradiated TiO~2~ and Related Metal Oxide Surfaces/46f349f61b538abc87f606d7dba94862.pdf

scihub/10.4028/www.scientific.net/ssp.162.1.pdf

zlib/no-category/Janusz Nowotny; Maria K Nowotny/Solid state chemistry and photocatalysis of titanium dioxide : special topic volume with invited peer reviewed papers only_2360849.pdf

Molecular Mechanism of Water Oxidation Reaction at Photo-Irradiated TiO~2~ and Related Metal Oxide Surfaces

Maria K. Nowotny, Janusz Nowotny, Janusz Nowotny

Janusz Nowotny; Maria K Nowotny

Diffusion and defect data., Pt. B,, Solid state phenomena ;, v. 162, 2010

Diffusion and defect data, v. 162, Stafa-Zuerich, 2010

Trans Tech Publications, Ltd, Stafa-Zuerich, 2010

Diffusion and defect data, Stafa-Zurich, 2009

Switzerland, Switzerland

lg1192402

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Referenced by: doi:10.1038/238037a0 doi:10.1038/440295a doi:10.1021/cr00033a004 doi:10.1016/s1389-5567(00)00002-2 doi:10.1149/1.2129624 doi:10.1016/0009-2614(82)83255-7 doi:10.1016/0039-6028(83)90799-9 doi:10.1016/s0022-0728(84)80119-9 doi:10.1021/j150660a064 doi:10.1016/0009-2614(82)83478-7 doi:10.1021/j100236a032 doi:10.1021/j100281a029 doi:10.1021/j100487a017 doi:10.1021/jp971315c doi:10.1039/b307433a doi:10.1246/cl.1985.1799 doi:10.1021/j100298a035 doi:10.1021/j100130a026 doi:10.1039/c39930000395 doi:10.1021/j100166a047 doi:10.1016/s1381-1169(03)00021-9 doi:10.1021/jp031305d doi:10.1021/la0361262 doi:10.1039/b314062h doi:10.1021/jp047736t doi:10.1021/jp0477351 doi:10.1016/j.cplett.2007.03.017 doi:10.1021/ja952155q doi:10.1021/jp0211988 doi:10.1021/jp020472v doi:10.1021/la015709d doi:10.1021/jp013784r doi:10.1246/cl.2002.420 doi:10.1039/c39800000543 doi:10.1016/0009-2614(80)80246-6 doi:10.1126/science.1061051 doi:10.1038/414625a doi:10.1002/anie.200351577 doi:10.1246/cl.2003.364 doi:10.1021/ja0269643 doi:10.1021/ja992541y doi:10.1039/b202393h doi:10.1021/jp027593f doi:10.1021/jp048112q doi:10.1021/jp0501289 doi:10.1149/1.2184496 doi:10.1021/jp070771q doi:10.1016/s0022-0728(03)00114-1 doi:10.1021/ja0388764 doi:10.1021/jp044710t doi:10.1021/ja053252e doi:10.1021/ja073206+ doi:10.1021/ja066041y doi:10.1021/jp063293c doi:10.1016/s1010-6030(00)00264-1 doi:10.1103/physrevlett.87.266103 doi:10.1016/0039-6028(91)91091-b doi:10.1016/s0167-5729(01)00020-6 doi:10.1021/jp074451i doi:10.1103/physrevlett.97.166803 doi:10.1016/0022-0728(95)04007-b doi:10.1021/jp962992u doi:10.1021/jp993285e doi:10.1021/ja029503q doi:10.1021/j100295a047 doi:10.1016/s0167-5729(02)00100-0 doi:10.1021/la036463a doi:10.1126/science.266.5190.1540 doi:10.1016/j.apsusc.2004.05.206 doi:10.1021/jp068012f doi:10.1021/la980855d doi:10.1021/jp012144l doi:10.1103/physrevlett.87.266104 doi:10.1016/0009-2614(81)80018-8 doi:10.1016/0009-2614(81)85456-5 doi:10.1063/1.555843 doi:10.1246/bcsj.71.2119

Content: Molecular Mechanism of Water Oxidation Reaction at Photo-Irradiated TiO2 and Related Metal Oxide Surfaces / Ryuhei Nakamura, Yoshihiro Nakato --
Development of Visible-Light-Driven TiO2 and SrTiO3 Photocatalysts Doped with Metal Cations for H2 or O2 Evolution / Ryo Niishiro, Akihiko Kudo --
Investigations of Photo-Excited TiO2 Based on Time Resolved Microwave Conductivity and Oxygen Isotopic Exchange / Pierre Pichat, Rosario Enriquez, Estelle Mietton --
Surface Modified Titania Visible Light Photocatalyst Powders / Dariusz Mitoraj, Horst Kisch --
Titanium Dioxide Photocatalyst --
Unresolved Problems / Tadeusz Bak, Truls Norby, Janusz Nowotny, Maria K. Nowotny, Nikolaus Sucher --
Tayloring the Photocatalytical Activity of Anatase TiO2 Thin Film Electrodes by Three-Dimensional Mesoporosity / Bernhard Neumann, Thorsten Brezesinsky, Bernd Smarsly, Helmut Tributsch --
Surface Science Approach to Photochemistry of TiO2 / Akira Sasahara, Hiroshi Onishi --
Composite Titanium Dioxide Photocatalysts and the ''Adsorb & Shuttle'' Approach : A Review / Yaron Paz --
X-Ray Photoelectron Spectroscopy of Anatase-TiO2 Coated Carbon Nanotubes / Pyrgiotakis Georgios, Sigmund M. Wolfgang --
Efficient Photoelectrochemical Splitting of Water to H2 and O2 at Nanocrystalline Carbon Modified (CM)-n-TiO2 Thin Films / Yasser A. Shaban, Shahed U. M. Khan.
Abstract: A special volume that intends to provide an opportunity to exchange information, to present the results and to review relevant issues affecting contemporary diffusion research. It includes large number (over 232) of peer-reviewed papers that emphasizes the considerable academic and industrial interest in this field. Read more...

The goal of this special volume was to provide a unique opportunity to exchange information, to present the latest results and to review relevant issues affecting contemporary diffusion research. The large number (over 232) of peer-reviewed papers emphasizes the considerable academic and industrial interest in this field. This interesting book offers much food-for-thought concerning the topic.

Volume Is Indexed By Thomson Reuters Bci (wos). The Goal Of This Special Volume Was To Provide A Unique Opportunity To Exchange Information, To Present The Latest Results And To Review Relevant Issues Affecting Contemporary Diffusion Research. The Large Number (over 232) Of Peer-reviewed Papers Emphasizes The Considerable Academic And Industrial Interest In This Field.

2014-07-04